Advances in water-splitting catalysts
Creating a hydrogen economy is no small task, but Rice University engineers have discovered a method that could make oxygen evolution catalysis in acids, one of the most challenging topics in water electrolysis for producing clean hydrogen fuels, more economical and practical.
The lab of chemical and biomolecular engineer Haotian Wang at Rice’s George R. Brown School of Engineering has replaced rare and expensive iridium with ruthenium, a far more abundant precious metal, as the positive-electrode catalyst in a reactor that splits water into hydrogen and oxygen.
The lab’s successful addition of nickel to ruthenium dioxide (RuO2) resulted in a robust anode catalyst that produced hydrogen from water electrolysis for thousands of hours under ambient conditions.
“There’s huge industry interest in clean hydrogen,” Wang said. “It’s an important energy carrier and also important for chemical fabrication, but its current production contributes a significant portion of carbon emissions in the chemical manufacturing sector globally. We want to produce it in a more sustainable way, and water-splitting using clean electricity is widely recognized as the most promising option.”
Iridium costs roughly eight times more than ruthenium, he said, and it could account for 20% to 40% of the expense in commercial device manufacturing, especially in future large-scale deployments.
The process developed by Wang, Rice postdoctoral associate Zhen-Yu Wu and graduate student Feng-Yang Chen, and colleagues at the University of Pittsburgh and the University of Virginia is detailed in Nature Materials.
Water splitting involves the oxygen and hydrogen evolution reactions by which polarized catalysts rearrange water molecules to release oxygen and hydrogen. “Hydrogen is produced by the cathode, which is a negative electrode,” Wu said. “At the same time, it has to balance the charge by oxidizing water to generate oxygen on the anode side.” More