Spin keeps electrons in line in iron-based superconductor
Researchers from PSI’s Spectroscopy of Quantum Materials group together with scientists from Beijing Normal University have solved a puzzle at the forefront of research into iron-based superconductors: the origin of FeSe’s electronic nematicity. Using Resonant inelastic X-ray scattering (RIXS) at the Swiss Light Source (SLS), they discovered that, surprisingly, this electronic phenomenon is primarily spin driven. Electronic nematicity is believed to be an important ingredient in high-temperature superconductivity, but whether it helps or hinders it is still unknown. Their findings are published in Nature Physics.
Near PSI, where the Swiss forest is ever present in people’s lives, you often see log piles: incredibly neat log piles. Wedge shaped logs for firewood are stacked carefully lengthways but with little thought to their rotation. When particles in a material spontaneously line up, like the logs in these log piles, such that they break rotational symmetry but preserve translational symmetry, a material is said to be in a nematic state. In a liquid crystal, this means that the rod shaped molecules are able to flow like a liquid in the direction of their alignment, but not in other directions. Electronic nematicity occurs when the electron orbitals in a material align in this way. Typically, this electronic nematicity manifests itself as anisotropic electronic properties: for example, resistivity or conductivity exhibiting vastly different magnitudes when measured along different axes.
Since their discovery in 2008, the past decade has seen enormous interest in the family of iron based superconductors. Alongside the well-studied cuprate superconductors, these materials exhibit the mysterious phenomenon of high temperature superconductivity. The electronic nematic state is a ubiquitous feature of iron-based superconductors. Yet, until now, the physical origin of this electronic nematicity is a puzzle; in fact, arguably one of the most important puzzles in the study of iron-based superconductors.
But why is the electronic nematicity so interesting? The answer lies with the ever exciting conundrum: understanding how electrons pair up and achieve superconductivity at high temperatures. The stories of electronic nematicity and superconductivity are inextricably linked — but exactly how, and indeed whether they compete or cooperate, is a hotly debated issue.
The drive to understand electronic nematicity has led researchers to turn their attention to one particular iron-based superconductor, iron selenide (FeSe). FeSe is somewhat of an enigma, simultaneously possessing the most simple crystal structure of all the iron-based superconductors and the most baffling electronic properties.
FeSe enters its superconducting phase below a critical temperature (Tc) of 9 K but tantalisingly boasts a tunable Tc, meaning that this temperaturecan be raised by applying pressure to or doping the material. The quasi-2D layered material possesses an extended electronic nematic phase, which appears below approximately 90 K. Curiously, this electronic nematicity appears without the long-range magnetic order that it would typically go hand in hand with, leading to lively debate surrounding its origins: namely, whether these are driven by orbital- or spin-degrees of freedom. The absence of long range magnetic order in FeSe gives the opportunity to have a clearer view on the electronic nematicity and its interplay with superconductivity. As a result many researchers feel that FeSe may hold the key to understanding the puzzle of electronic nematicity across the family of iron based superconductors. More