After 20 years of trying, scientists succeed in doping a 1D chain of cuprates
When scientists study unconventional superconductors — complex materials that conduct electricity with zero loss at relatively high temperatures — they often rely on simplified models to get an understanding of what’s going on.
Researchers know these quantum materials get their abilities from electrons that join forces to form a sort of electron soup. But modeling this process in all its complexity would take far more time and computing power than anyone can imagine having today. So for understanding one key class of unconventional superconductors — copper oxides, or cuprates — researchers created, for simplicity, a theoretical model in which the material exists in just one dimension, as a string of atoms. They made these one-dimensional cuprates in the lab and found that their behavior agreed with the theory pretty well.
Unfortunately, these 1D atomic chains lacked one thing: They could not be doped, a process where some atoms are replaced by others to change the number of electrons that are free to move around. Doping is one of several factors scientists can adjust to tweak the behavior of materials like these, and it’s a critical part of getting them to superconduct.
Now a study led by scientists at the Department of Energy’s SLAC National Accelerator Laboratory and Stanford and Clemson universities has synthesized the first 1D cuprate material that can be doped. Their analysis of the doped material suggests that the most prominent proposed model of how cuprates achieve superconductivity is missing a key ingredient: an unexpectedly strong attraction between neighboring electrons in the material’s atomic structure, or lattice. That attraction, they said, may be the result of interactions with natural lattice vibrations.
The team reported their findings today in Science.
“The inability to controllably dope one-dimensional cuprate systems has been a significant barrier to understanding these materials for more than two decades,” said Zhi-Xun Shen, a Stanford professor and investigator with the Stanford Institute for Materials and Energy Sciences (SIMES) at SLAC. More

