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    Sustainable silk material for biomedical, optical, food supply applications

    While silk is best known as a component in clothes and fabric, the material has plentiful uses, spanning biomedicine to environmental science. In Applied Physics Reviews, by AIP Publishing, researchers from Tufts University discuss the properties of silk and recent and future applications of the material.
    Silk makes an important biomaterial, because it does not generate an immune response in humans and promotes the growth of cells. It has been used in drug delivery, and because the material is flexible and has favorable technological properties, it is ideal for wearable and implantable health monitoring sensors.
    As an optically transparent and easily manipulated material at the nano- and microscale, silk is also useful in optics and electronics. It is used to develop diffractive optics, photonic crystals, and waveguides, among other devices.
    More recently, silk has come to the forefront of sustainability research. The material is made in nature and can be reprocessed from recycled or discarded clothing and other textiles. The use of silk coatings may also reduce food waste, which is a significant component of the global carbon footprint.
    “We are continuing to improve the integration between different disciplines,” said author Giulia Guidetti. “For example, we can use silk as a biomedical device for drug delivery but also include an optical response in that same device. This same process could be used someday in the food supply chain. Imagine having a coating which preserves the food but also tells you when the food is spoiled.”
    Silk is versatile and often superior to more traditional materials, because it can be easily chemically modified and tuned for certain properties or assembled into a specific form depending on its final use. However, controlling and optimizing these aspects depends on understanding the material’s origin.
    The bottom-up assembly of silk by silkworms has been studied for a long time, but a full picture of its construction is still lacking. The team emphasized the importance of understanding these processes, because it could allow them to fabricate the material more effectively and with more control over the final function.
    “One big challenge is that nature is very good at doing things, like making silk, but it covers an enormous dimensional parameter space,” said author Fiorenzo Omenetto. “For technology, we want to make something with repeatability, which requires being able to control a process that has inherent variability and has been perfected over thousands of years.”
    The scientists hope to see more materials and devices use silk in the future, possibly as an integral component in sensors to obtain emergent data on humans and the environment.
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    Resolving the black hole ‘fuzzball or wormhole’ debate

    Black holes really are giant fuzzballs, a new study says.
    The study attempts to put to rest the debate over Stephen Hawking’s famous information paradox, the problem created by Hawking’s conclusion that any data that enters a black hole can never leave. This conclusion accorded with the laws of thermodynamics, but opposed the fundamental laws of quantum mechanics.
    “What we found from string theory is that all the mass of a black hole is not getting sucked in to the center,” said Samir Mathur, lead author of the study and professor of physics at The Ohio State University. “The black hole tries to squeeze things to a point, but then the particles get stretched into these strings, and the strings start to stretch and expand and it becomes this fuzzball that expands to fill up the entirety of the black hole.”
    The study, published Dec. 28 in the Turkish Journal of Physics, found that string theory almost certainly holds the answer to Hawking’s paradox, as the paper’s authors had originally believed. The physicists proved theorems to show that the fuzzball theory remains the most likely solution for Hawking’s information paradox. The researchers have also published an essay showing how this work may resolve longstanding puzzles in cosmology; the essay appeared in December in the International Journal of Modern Physics.
    Mathur published a study in 2004 that theorized black holes were similar to very large, very messy balls of yarn — “fuzzballs” that become larger and messier as new objects get sucked in.
    “The bigger the black hole, the more energy that goes in, and the bigger the fuzzball becomes,” Mathur said. The 2004 study found that string theory, the physics theory that holds that all particles in the universe are made of tiny vibrating strings, could be the solution to Hawking’s paradox. With this fuzzball structure, the hole radiates like any normal body, and there is no puzzle. More

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    Simple, accurate, and efficient: Improving the way computers recognize hand gestures

    In the 2002 science fiction blockbuster film Minority Report, Tom Cruise’s character John Anderton uses his hands, sheathed in special gloves, to interface with his wall-sized transparent computer screen. The computer recognizes his gestures to enlarge, zoom in, and swipe away. Although this futuristic vision for computer-human interaction is now 20 years old, today’s humans still interface with computers by using a mouse, keyboard, remote control, or small touch screen. However, much effort has been devoted by researchers to unlock more natural forms of communication without requiring contact between the user and the device. Voice commands are a prominent example that have found their way into modern smartphones and virtual assistants, letting us interact and control devices through speech.
    Hand gestures constitute another important mode of human communication that could be adopted for human-computer interactions. Recent progress in camera systems, image analysis, and machine learning have made optical-based gesture recognition a more attractive option in most contexts than approaches relying on wearable sensors or data gloves, as used by Anderton in Minority Report. However, current methods are hindered by a variety of limitations, including high computational complexity, low speed, poor accuracy, or a low number of recognizable gestures. To tackle these issues, a team led by Zhiyi Yu of Sun Yat-sen University, China, recently developed a new hand gesture recognition algorithm that strikes a good balance between complexity, accuracy, and applicability. As detailed in their paper, which was published in the Journal of Electronic Imaging, the team adopted innovative strategies to overcome key challenges and realize an algorithm that can be easily applied in consumer-level devices.
    One of the main features of the algorithm is adaptability to different hand types. The algorithm first tries to classify the hand type of the user as either slim, normal, or broad based on three measurements accounting for relationships between palm width, palm length, and finger length. If this classification is successful, subsequent steps in the hand gesture recognition process only compare the input gesture with stored samples of the same hand type. “Traditional simple algorithms tend to suffer from low recognition rates because they cannot cope with different hand types. By first classifying the input gesture by hand type and then using sample libraries that match this type, we can improve the overall recognition rate with almost negligible resource consumption,” explains Yu.
    Another key aspect of the team’s method is the use of a “shortcut feature” to perform a prerecognition step. While the recognition algorithm is capable of identifying an input gesture out of nine possible gestures, comparing all the features of the input gesture with those of the stored samples for all possible gestures would be very time consuming. To solve this problem, the prerecognition step calculates a ratio of the area of the hand to select the three most likely gestures of the possible nine. This simple feature is enough to narrow down the number of candidate gestures to three, out of which the final gesture is decided using a much more complex and high-precision feature extraction based on “Hu invariant moments.” Yu says, “The gesture prerecognition step not only reduces the number of calculations and hardware resources required but also improves recognition speed without compromising accuracy.”
    The team tested their algorithm both in a commercial PC processor and an FPGA platform using an USB camera. They had 40 volunteers make the nine hand gestures multiple times to build up the sample library, and another 40 volunteers to determine the accuracy of the system. Overall, the results showed that the proposed approach could recognize hand gestures in real time with an accuracy exceeding 93%, even if the input gesture images were rotated, translated, or scaled. According to the researchers, future work will focus on improving the performance of the algorithm under poor lightning conditions and increasing the number of possible gestures.
    Gesture recognition has many promising fields of application and could pave the way to new ways of controlling electronic devices. A revolution in human-computer interaction might be close at hand!
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    Materials provided by SPIE–International Society for Optics and Photonics. Note: Content may be edited for style and length. More

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    ‘Pop-up’ electronic sensors could detect when individual heart cells misbehave

    Engineers at the University of California San Diego have developed a powerful new tool that monitors the electrical activity inside heart cells, using tiny “pop-up” sensors that poke into cells without damaging them. The device directly measures the movement and speed of electrical signals traveling within a single heart cell — a first — as well as between multiple heart cells. It is also the first to measure these signals inside the cells of 3D tissues.
    The device, published Dec. 23 in the journal Nature Nanotechnology, could enable scientists to gain more detailed insights into heart disorders and diseases such as arrhythmia (abnormal heart rhythm), heart attack and cardiac fibrosis (stiffening or thickening of heart tissue).
    “Studying how an electrical signal propagates between different cells is important to understand the mechanism of cell function and disease,” said first author Yue Gu, who recently received his Ph.D. in materials science and engineering at UC San Diego. “Irregularities in this signal can be a sign of arrhythmia, for example. If the signal cannot propagate correctly from one part of the heart to another, then some part of the heart cannot receive the signal so it cannot contract.”
    “With this device, we can zoom in to the cellular level and get a very high resolution picture of what’s going on in the heart; we can see which cells are malfunctioning, which parts are not synchronized with the others, and pinpoint where the signal is weak,” said senior author Sheng Xu, a professor of nanoengineering at the UC San Diego Jacobs School of Engineering. “This information could be used to help inform clinicians and enable them to make better diagnoses.”
    The device consists of a 3D array of microscopic field effect transistors, or FETs, that are shaped like sharp pointed tips. These tiny FETs pierce through cell membranes without damaging them and are sensitive enough to detect electrical signals — even very weak ones — directly inside the cells. To evade being seen as a foreign substance and remain inside the cells for long periods of time, the FETs are coated in a phospholipid bilayer. The FETs can monitor signals from multiple cells at the same time. They can even monitor signals at two different sites inside the same cell.
    “That’s what makes this device unique,” said Gu. “It can have two FET sensors penetrate inside one cell — with minimal invasiveness — and allow us to see which way a signal propagates and how fast it goes. This detailed information about signal transportation within a single cell has so far been unknown.”
    To build the device, the team first fabricated the FETs as 2D shapes, and then bonded select spots of these shapes onto a pre-stretched elastomer sheet. The researchers then loosened the elastomer sheet, causing the device to buckle and the FETs to fold into a 3D structure so that they can penetrate inside cells. More

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    Novel semiconductor gives new perspective on anomalous Hall effect

    A large, unconventional anomalous Hall resistance in a new magnetic semiconductor in the absence of large-scale magnetic ordering has been demonstrated by Tokyo Tech materials scientists, validating a recent theoretical prediction. Their findings provide new insights into the anomalous Hall effect, a quantum phenomenon that has previously been associated with long-range magnetic order.
    Charged particles such as electrons can behave in interacting ways when moving under the influence of electric and magnetic fields. For instance, when a magnetic field is applied perpendicular to the plane of a current-carrying conductor, the electrons flowing within start to deviate sideways due to magnetic force and soon enough, a voltage difference appears across the conductor. This phenomenon is famously called the “Hall effect.” However, the Hall effect does not necessarily require fiddling with magnets. In fact, it can be observed in magnetic materials with long-range magnetic order, such as ferromagnets, for free!
    Named “anomalous Hall effect” (AHE), this phenomenon appears to be a close cousin of the Hall effect. However, its mechanism is way more involved. Currently, the most accepted one is that the AHE is produced by a property of the electronic energy bands called “Berry curvature,” which results from an interaction between the electron’s spin and its motion inside the material, more commonly known as “spin-orbit interaction.”
    Is magnetic ordering necessary for AHE? A recent theory suggests otherwise. “It has been theoretically proposed that a large AHE is possible even above the temperature at which the magnetic order vanishes, especially in magnetic semiconductors with low charge carrier density, strong exchange interaction between electrons, and finite spin chirality, which relates to the spin direction with respect to the direction of motion,” explains Associate Professor Masaki Uchida from Tokyo Institute of Technology (Tokyo Tech), whose research focus lies in condensed matter physics.
    Curious, Dr. Uchida and his collaborators from Japan decided to put this theory to the test. In a new study published in Science Advances, they investigated the magnetic properties of a new magnetic semiconductor EuAs that is only known to have a peculiar distorted triangular lattice structure and observed an antiferromagnetic (AFM) behavior (neighboring electron spins aligned in opposite directions) below 23 K. Furthermore, they observed that the material’s electrical resistance dropped dramatically with temperature in the presence of an external magnetic field, a behavior known as “colossal magnetoresistance” (CMR). However, more interestingly, the CMR was observed even above 23 K, where the AFM order vanished.
    “It is naturally understood that the CMR observed in EuAs is caused by a coupling between the diluted carriers and localized Eu2+ spins that persist over a wide range of temperatures,” comments Dr. Uchida.
    What really stole the show, however, was the rise in Hall resistivity with temperature, which peaked at a temperature of 70 K, far above the AFM ordering temperature, demonstrating that large AHE was indeed possible without magnetic order. To understand what caused this unconventionally large AHE, the team performed model calculations, which showed that the effect could be attributed to a skew scattering of electrons by a spin cluster on the triangular lattice in a “hopping regime” where the electrons did not flow but rather “hopped” from atom to atom.
    These results bring us one step closer to understanding the strange behavior of electrons inside magnetic solids. “Our findings have helped shed light on triangular-lattice magnetic semiconductors and could potentially lead to a new field of research targeting diluted carriers coupled to unconventional spin orderings and fluctuations,” comments an optimistic Dr. Uchida.
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    A-list candidate for fault-free quantum computing delivers surprise

    A Rice University-led study is forcing physicists to rethink superconductivity in uranium ditelluride, an A-list material in the worldwide race to create fault-tolerant quantum computers.
    Uranium ditelluride crystals are believed to host a rare “spin-triplet” form of superconductivity, but puzzling experimental results published this week in Nature have upended the leading explanation of how the state of matter could arise in the material. Neutron-scattering experiments by physicists from Rice, Oak Ridge National Laboratory, the University of California, San Diego and the National High Magnetic Field Laboratory at Florida State University revealed telltale signs of antiferromagnetic spin fluctuations that were coupled to superconductivity in uranium ditelluride.
    Spin-triplet superconductivity has not been observed in a solid-state material, but physicists have long suspected it arises from an ordered state that is ferromagnetic. The race to find spin-triplet materials has heated up in recent years due to their potential for hosting elusive quasiparticles called Majorana fermions that could be used to make error-free quantum computers.
    “People have spent billions of dollars trying to search for them,” Rice study co-author Pengcheng Dai said of Majorana fermions, hypothetical quasiparticles that could be used to make topological quantum bits free from the problematic decoherence that plagues qubits in today’s quantum computers.
    “The promise is that if you have a spin-triplet superconductor, it can potentially be used to make topological qubits,” said Dai, a professor of physics and astronomy and member of the Rice Quantum Initiative. “You can’t do that with spin-singlet superconductors. So, that’s why people are extremely interested in this.”
    Superconductivity happens when electrons form pairs and move as one, like couples spinning across a dance floor. Electrons naturally loathe one another, but their tendency to avoid other electrons can be overcome by their inherent desire for a low-energy existence. If pairing allows electrons to achieve a more sloth-like state than they could achieve on their own — something that’s only possible at extremely cold temperatures — they can be coaxed into pairs. More

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    Fabrication of flexible electronics improved using gold and water-vapor plasma

    Researchers at the RIKEN Center for Emergent Matter Science (CEMS) and the RIKEN Cluster for Pioneering Research (CPR) in Japan have developed a technique to improve the flexibility of ultra-thin electronics, such as those used in bendable devices or clothing. Published in Science Advances, the study details the use of water vapor plasma to directly bond gold electrodes fixed onto separate ultra-thin polymer films, without needing adhesives or high temperatures.
    As electronic devices get smaller and smaller, and the desire to have bendable, wearable, and on-skin electronics increases, conventional methods of constructing these devices have become impractical. One of the biggest problems is how to connect and integrate multiple devices or pieces of a device that each reside on separate ultra-thin polymer films. Conventional methods that use layers of adhesive to stick electrodes together reduce flexibility and require temperature and pressure that are damaging to super-thin electronics. Conventional methods of direct metal-to-metal bonding are available, but require perfectly smooth and clean surfaces that are not typical in these types of electronics.
    A team of researchers led by Takao Someya at RIKEN CEMS/CPR has developed a new method to secure these connections that does not use adhesive, high temperature, or high pressure, and does not require totally smooth or clean surfaces. In fact, the process takes less than a minute at room temperature, followed by about a 12-hour wait. The new technique, called water-vapor plasma-assisted bonding, creates stable bonds between gold electrodes that are printed into ultra-thin — 2 thousandths of a millimeter! — polymer sheets using a thermal evaporator.
    “This is the first demonstration of ultra-thin, flexible gold electronics fabricated without any adhesive,” says Senior Research Scientist Kenjiro Fukuda of RIKEN CEMS/CPR. “Using this new direct bond technology, we were able to fabricate an integrated system of flexible organic solar cells and organic LEDs.” Experiments showed that water-vapor plasma-assisted bonding performed better that conventional adhesive or direct bonding techniques. In particular, the strength and consistency of the bonds were greater than what standard surface-assisted direct bonding achieved. At the same time, the material conformed better to curved surfaces and was more durable than what could be achieved using a standard adhesive technique.
    According to Fukuda, the method itself is surprisingly simple, which might explain why they discovered it by accident. After fixing the gold electrodes onto polymer sheets, a machine is used to expose the electrode sides of the sheets to water-vapor plasma for 40 seconds. Then, the polymer sheets are pressed together so that the electrodes overlap in the correct location. After waiting 12 hours in room temperature, they are ready to use. Another advantage of this system is that after activation with water-vapor plasma, but before being bonded together, the films can be stored in vacuum packs for days. This is an important practical aspect when considering the potential for ordering and distributing pre-activated components.
    As proof of concept, the team integrated ultra-thin organic photovoltaic and LED-light modules that were printed on separate films and connected by five additional polymer films. The devices withstood extensive testing, including being wrapped around a stick and being crumpled and twisted to extremes. Additionally, the power efficiency of the LEDs did not suffer from the treatment. The technique was also able to join pre-packaged LED chips to a flexible surface.
    “We expect this new method to become a flexible wiring and mounting technology for next-generation wearable electronics that can be attached to clothes and skin,” says Fukuda. “The next step is to develop this technology for use with cheaper metals, such as copper or aluminum.”
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    Semiconductors reach the quantum world

    Quantum effects in superconductors could give semiconductor technology a new twist. Researchers at the Paul Scherrer Institute PSI and Cornell University in New York State have identified a composite material that could integrate quantum devices into semiconductor technology, making electronic components significantly more powerful. They publish their findings today in the journal Science Advances.
    Our current electronic infrastructure is based primarily on semiconductors. This class of materials emerged around the middle of the 20th century and has been improving ever since. Currently, the most important challenges in semiconductor electronics include further improvements that would increase the bandwidth of data transmission, energy efficiency and information security. Exploiting quantum effects is likely to be a breakthrough.
    Quantum effects that can occur in superconducting materials are particularly worthy of consideration. Superconductors are materials in which the electrical resistance disappears when they are cooled below a certain temperature. The fact that quantum effects in superconductors can be utilised has already been demonstrated in first quantum computers.
    To find possible successors for today’s semiconductor electronics, some researchers — including a group at Cornell University — are investigating so-called heterojunctions, i.e. structures made of two different types of materials. More specifically, they are looking at layered systems of superconducting and semiconducting materials. “It has been known for some time that you have to select materials with very similar crystal structures for this, so that there is no tension in the crystal lattice at the contact surface,” explains John Wright, who produced the heterojunctions for the new study at Cornell University.
    Two suitable materials in this respect are the superconductor niobium nitride (NbN) and the semiconductor gallium nitride (GaN). The latter already plays an important role in semiconductor electronics and is therefore well researched. Until now, however, it was unclear exactly how the electrons behave at the contact interface of these two materials — and whether it is possible that the electrons from the semiconductor interfere with the superconductivity and thus obliterate the quantum effects.
    “When I came across the research of the group at Cornell, I knew: here at PSI we can find the answer to this fundamental question with our spectroscopic methods at the ADRESS beamline,” explains Vladimir Strocov, researcher at the Synchrotron Light Source SLS at PSI.
    This is how the two groups came to collaborate. In their experiments, they eventually found that the electrons in both materials “keep to themselves.” No unwanted interaction that could potentially spoil the quantum effects takes place.
    Synchrotron light reveals the electronic structures
    The PSI researchers used a method well-established at the ADRESS beamline of the SLS: angle-resolved photoelectron spectroscopy using soft X-rays — or SX-ARPES for short. “With this method, we can visualise the collective motion of the electrons in the material,” explains Tianlun Yu, a postdoctoral researcher in Vladimir Strocov’s team, who carried out the measurements on the NbN/GaN heterostructure. Together with Wright, Yu is the first author of the new publication.
    The SX-ARPES method provides a kind of map whose spatial coordinates show the energy of the electrons in one direction and something like their velocity in the other; more precisely, their momentum. “In this representation, the electronic states show up as bright bands in the map,” Yu explains. The crucial research result: at the material boundary between the niobium nitride NbN and the gallium nitride GaN, the respective “bands” are clearly separated from each other. This tells the researchers that the electrons remain in their original material and do not interact with the electrons in the neighbouring material.
    “The most important conclusion for us is that the superconductivity in the niobium nitride remains undisturbed, even if this is placed atom by atom to match a layer of gallium nitride,” says Vladimir Strocov. “With this, we were able to provide another piece of the puzzle that confirms: This layer system could actually lend itself to a new form of semiconductor electronics that embeds and exploits the quantum effects that happen in superconductors.”
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    Materials provided by Paul Scherrer Institute. Original written by Laura Hennemann. Note: Content may be edited for style and length. More