Smuggling light through opaque materials
Electrical engineers at Duke University have discovered that changing the physical shape of a class of materials commonly used in electronics and near- and mid-infrared photonics — chalcogenide glasses — can extend their use into the visible and ultraviolet parts of electromagnetic spectrum. Already commercially used in detectors, lenses and optical fibers, chalcogenide glasses may now find a home in applications such as underwater communications, environmental monitoring and biological imaging.
The results appear online on October 5 in the journal Nature Communications.
As the name implies, chalcogenide glasses contain one or more chalcogens — chemical elements such as sulfur, selenium and tellurium. But there’s one member of the family they leave out: oxygen. Their material properties make them a strong choice for advanced electronic applications such as optical switching, ultra-small direct laser writing (think tiny rewritable CDs) and molecular fingerprinting. But because they strongly absorb wavelengths of light in the visible and ultraviolet parts of electromagnetic spectrum, chalcogenide glasses have long been constrained to the near- and mid-infrared with respect to their applications in photonics.
“Chalcogenides have been used in the near- and mid-IR for a long time, but they’ve always had this fundamental limitation of being lossy at visible and UV wavelengths,” said Natalia Litchinitser, professor of electrical and computer engineering at Duke. “But recent research into how nanostructures affect the way these materials respond to light indicated that there might be a way around these limitations.”
In recent theoretical research into the properties of gallium arsenide (GaAs), a semiconductor commonly used in electronics, Litchinitser’ s collaborators, Michael Scalora of the US Army CCDC Aviation and Missile Center and Maria Vincenti of the University of Brescia predicted that nanostructured GaAs might respond to light differently than its bulk or even thin film counterparts. Because of the way that high intensity optical pulses interact with the nanostructured material, very thin wires of the material lined up next to one another might create higher-order harmonic frequencies (shorter wavelengths) that could travel through them.
Imagine a guitar string that is tuned to resonate at 256 Hertz — otherwise known as middle C. The researchers were proposing that if fabricated just right, this string when plucked might also vibrate at frequencies one or two octaves higher in small amounts. More