Scientists studying two different configurations of bilayer graphene — the two-dimensional (2-D), atom-thin form of carbon — have detected electronic and optical interlayer resonances. In these resonant states, electrons bounce back and forth between the two atomic planes in the 2-D interface at the same frequency. By characterizing these states, they found that twisting one of the graphene layers by 30 degrees relative to the other, instead of stacking the layers directly on top of each other, shifts the resonance to a lower energy. From this result, just published in Physical Review Letters, they deduced that the distance between the two layers increased significantly in the twisted configuration, compared to the stacked one. When this distance changes, so do the interlayer interactions, influencing how electrons move in the bilayer system. An understanding of this electron motion could inform the design of future quantum technologies for more powerful computing and more secure communication.
“Today’s computer chips are based on our knowledge of how electrons move in semiconductors, specifically silicon,” said first and co-corresponding author Zhongwei Dai, a postdoc in the Interface Science and Catalysis Group at the Center for Functional Nanomaterials (CFN) at the U.S. Department of Energy (DOE)’s Brookhaven National Laboratory. “But the physical properties of silicon are reaching a physical limit in terms of how small transistors can be made and how many can fit on a chip. If we can understand how electrons move at the small scale of a few nanometers in the reduced dimensions of 2-D materials, we may be able to unlock another way to utilize electrons for quantum information science.”
At a few nanometers, or billionths of a meter, the size of a material system is comparable to that of the wavelength of electrons. When electrons are confined in a space with dimensions of their wavelength, the material’s electronic and optical properties change. These quantum confinement effects are the result of quantum mechanical wave-like motion rather than classical mechanical motion, in which electrons move through a material and are scattered by random defects.
For this research, the team selected a simple material model — graphene — to investigate quantum confinement effects, applying two different probes: electrons and photons (particles of light). To probe both electronic and optical resonances, they used a special substrate onto which the graphene could be transferred. Co-corresponding author and CFN Interface Science and Catalysis Group scientist Jurek Sadowski had previously designed this substrate for the Quantum Material Press (QPress). The QPress is an automated tool under development in the CFN Materials Synthesis and Characterization Facility for the synthesis, processing, and characterization of layered 2-D materials. Conventionally, scientists exfoliate 2-D material “flakes” from 3-D parent crystals (e.g., graphene from graphite) on a silicon dioxide substrate several hundred nanometers thick. However, this substrate is insulating, and thus electron-based interrogation techniques don’t work. So, Sadowski and CFN scientist Chang-Yong Nam and Stony Brook University graduate student Ashwanth Subramanian deposited a conductive layer of titanium oxide only three nanometers thick on the silicon dioxide substrate.
“This layer is transparent enough for optical characterization and determination of the thickness of exfoliated flakes and stacked monolayers while conductive enough for electron microscopy or synchrotron-based spectroscopy techniques,” explained Sadowski.
In the Charlie Johnson Group at the University of Pennsylvania — Rebecca W. Bushnell Professor of Physics and Astronomy Charlie Johnson, postdoc Qicheng Zhang, and former postdoc Zhaoli Gao (now an assistant professor at the Chinese University of Hong Kong) — grew the graphene on metal foils and transferred it onto the titanium oxide/silicon dioxide substrate. When graphene is grown in this way, all three domains (single layer, stacked, and twisted) are present. More