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    A materials scientist seeks to extract lithium from untapped sources

    Electric vehicles promise to help wean us off of fossil fuels, but they introduce a new problem: how to get enough of the lithium that EV batteries require (SN: 5/7/19).

    Materials scientist Chong Liu of the University of Chicago has some ideas. Existing technology can extract lithium only from sources with highly concentrated ions, like hard rocks or underground deposits of salty water called brines. Not only will those sources not be enough to meet demand, but mining them also comes with environmental consequences (SN: 3/15/22). More

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    Jurassic Park’s amber-preserved dino DNA is now inspiring a way to store data 

    Sometimes science fiction does inspire science research. À la Jurassic Park’s entombed mosquito, scientists have developed a method to store DNA in an amberlike material and still extract it easily hours later. This storage method is cheaper and faster than existing options, the researchers report in the June Journal of the American Chemical Society.

    If you want to store information for a very long time, possibly forever, DNA is the way to do it, says James Banal, a chemist at MIT and technical director of a biotechnology company called Cache DNA, headquartered in San Carlos, Calif. DNA stores the genetic information of millions of organisms, but it can potentially be used to store any kind of information, including digital data such as text, photos, videos and more (SN: 10/2/19). More

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    Artificial intelligence helped scientists create a new type of battery 

    In the hunt for new materials, scientists have traditionally relied on tinkering in the lab, guided by intuition, with a hefty serving of trial and error.

    But now a new battery material has been discovered by combining two computing superpowers: artificial intelligence and supercomputing. It’s a discovery that highlights the potential for using computers to help scientists discover materials suited to specific needs, from batteries to carbon capture technologies to catalysts. 

    Calculations winnowed down more than 32 million candidate materials to just 23 promising options, researchers from Microsoft and Pacific Northwest National Laboratory, or PNNL, report in a paper submitted January 8 to arXiv.org. The team then synthesized and tested one of those materials and created a working battery prototype. More

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    This ‘thermal cloak’ keeps spaces from getting either too hot or cold

    If you’ve ever burned your hands on a car steering wheel, you know how hot the inside of a car can get on a summer day. But a new fabric could one day help cars and other objects stay cool in the summer and warm in the winter.

    Researchers created a prototype of the fabric, which acts as a “thermal cloak” that keeps the space underneath it from getting too hot or too cold. The cloak, described in the July 11 Device, doesn’t require an external power source, which could reduce energy consumption associated with heating and cooling (SN: 9/28/18).

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    Globally, heating and cooling make up 38 percent of energy use in buildings and 12 percent of total energy consumption. Materials like this thermal cloak could help keep us comfortable during heat waves while reducing carbon dioxide emissions associated with electricity used in temperature control, says Aaswath Raman, an applied physicist at UCLA who was not involved in the study.

    In the new study, Kehang Cui, an engineer at Shanghai Jiao Tong University, and colleagues built the cloak using two layers. The outer layer is made of white silica fibers that reflect visible light, coated with hexagonal boron nitride, a ceramic material that reflects ultraviolet light and helps dissipate heat. Together, the silica fibers and boron nitride reflect 96 percent of the sunlight that hits the fabric. At the same time, the outer layer absorbs heat from the surrounding area and emits that energy as infrared light, which also lowers the temperature under the cloak through a process called radiative cooling.

    Though the outer layer keeps the space under the cloak cooler for longer than an uncovered area, the cloaked space slowly warms up throughout the day. The inner layer, made of aluminum foil, keeps the space warm at night by trapping some of that heat inside, similar to an insulating survival blanket.

    The researchers tested the cloak material’s durability under several extreme conditions. They baked the fabric at 800° Celsius, just about hot enough to melt table salt. They also exposed it to extreme cold by dunking it in liquid nitrogen, subjected it to the same amount of vibration as a rocket launch, doused it in acid and blasted it with fire from a butane torch — all with virtually no changes to the material’s structure or performance. This extreme durability might lend itself to use in spacecraft or extraterrestrial environments, the team says.

    To see the fabric in action, Cui and colleagues built a full-size prototype cloak and tested it on an electric car. On a summer day in Shanghai, the cloak kept the car at about 23° C — up to 8 degrees C lower than the outside temperature and 28 degrees C lower than the inside of an uncloaked car. The cloak also kept the car about 5 degrees C warmer than the outside air on a winter night.

    The cloak “definitely shows the capability of saving energy, but the next step is that we want to demonstrate it in even larger-scale field tests [such as rooftops] to see the impact on our daily lives,” Cui says. More

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    A vegan leather made of dormant fungi can repair itself

    Imagine if a ripped leather jacket could repair itself instead of needing to be replaced.

    This could one day be a reality, if the jacket is fashioned from fungus, researchers report April 11 in Advanced Functional Materials. The team made a self-healing leather from mushrooms’ threadlike structures called mycelium, building on past iterations of the material to allow it to fix itself.

    Mycelium leather is already an emerging product, but it’s produced in a way that extinguishes fungal growth. Elise Elsacker and colleagues speculated that if the production conditions were tweaked, the mycelium could retain its ability to regrow if damaged.

    That novel approach could offer inspiration to other researchers trying to get into the mycelium leather market, says Valeria La Saponara, a mechanical and aerospace engineer at the University of California, Davis.

    Elsacker, a bioengineer now at the Vrije Universiteit Brussel, and her colleagues first grew mycelium in a soup rich in proteins, carbohydrates and other nutrients. A skin formed on the surface of the liquid, which the scientists scooped off, cleaned and dried to make a thin, somewhat fragile leather material. They used temperatures and chemicals mild enough to form the leather but leave parts of the fungus functional. Left dormant were chlamydospores, little nodules on the mycelium that can spring back to life and grow more mycelium when conditions are prime.

    After punching holes in the leather, the researchers doused the area in the same broth used to grow it to revive the chlamydospores. The mycelium eventually regrew over the punctures. Once healed, the hole-punched areas were just as strong as undamaged areas — however, the repairs were visible from one side of the leather.

    Chlamydospores are little nodules on fungi’s threadlike mycelium that can spring back to life. They’re dormant in the punctured leather (left). With the right nutrients, the chlamydospores reanimated and the leather healed itself (middle), but the tiny patches are still slightly visible in the repaired leather (right).E. Elsacker et al/Advanced Functional Materials, 2023

    The technique could potentially go beyond a proof-of-concept and into commercialization in the next decade, says study coauthor Martyn Dade-Robertson, codirector of the Hub for Biotechnology in the Built Environment in Newcastle upon Tyne. But first, the team will need to make the leather stronger and determine how to control the chlamydospores’ growth. Otherwise, he says, someone could “walk out in the rain, and then all of a sudden find that [their] jacket is growing, or perhaps [has] mushrooms popping out of it.”  More

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    These shape-shifting devices melt and re-form thanks to magnetic fields

    Shape-shifting liquid metal robots might not be limited to science fiction anymore.

    Miniature machines can switch from solid to liquid and back again to squeeze into tight spaces and perform tasks like soldering a circuit board, researchers report January 25 in Matter.

    This phase-shifting property, which can be controlled remotely with a magnetic field, is thanks to the metal gallium. Researchers embedded the metal with magnetic particles to direct the metal’s movements with magnets. This new material could help scientists develop soft, flexible robots that can shimmy through narrow passages and be guided externally.  

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    Scientists have been developing magnetically controlled soft robots for years. Most existing materials for these bots are made of either stretchy but solid materials, which can’t pass through the narrowest of spaces, or magnetic liquids, which are fluid but unable to carry heavy objects (SN: 7/18/19).

    In the new study, researchers blended both approaches after finding inspiration from nature (SN: 3/3/21). Sea cucumbers, for instance, “can very rapidly and reversibly change their stiffness,” says mechanical engineer Carmel Majidi of Carnegie Mellon University in Pittsburgh. “The challenge for us as engineers is to mimic that in the soft materials systems.”

    So the team turned to gallium, a metal that melts at about 30° Celsius — slightly above room temperature. Rather than connecting a heater to a chunk of the metal to change its state, the researchers expose it to a rapidly changing magnetic field to liquefy it. The alternating magnetic field generates electricity within the gallium, causing it to heat up and melt. The material resolidifies when left to cool to room temperature.

    Since magnetic particles are sprinkled throughout the gallium, a permanent magnet can drag it around. In solid form, a magnet can move the material at a speed of about 1.5 meters per second. The upgraded gallium can also carry about 10,000 times its weight.

    External magnets can still manipulate the liquid form, making it stretch, split and merge. But controlling the fluid’s movement is more challenging, because the particles in the gallium can freely rotate and have unaligned magnetic poles as a result of melting. Because of their various orientations, the particles move in different directions in response to a magnet.

    Majidi and colleagues tested their strategy in tiny machines that performed different tasks. In a demonstration straight out of the movie Terminator 2, a toy person escaped a jail cell by melting through the bars and resolidifying in its original form using a mold placed just outside the bars.

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    On the more practical side, one machine removed a small ball from a model human stomach by melting slightly to wrap itself around the foreign object before exiting the organ. But gallium on its own would turn to goo inside a real human body, since the metal is a liquid at body temperature, about 37° C. A few more metals, such as bismuth and tin, would be added to the gallium in biomedical applications to raise the material’s melting point, the authors say. In another demonstration, the material liquefied and rehardened to solder a circuit board.

    [embedded content]
    With the help of variable and permanent magnets, researchers turned chunks of gallium into shape-shifting devices. In the first clip, a toy figure escapes its jail cell by liquefying, gliding through the bars and resolidifying using a mold placed just outside the bars. In the second clip, one device removes a ball from a model human stomach by melting slightly to wrap itself around the foreign object and exiting the organ.

    Although this phase-shifting material is a big step in the field, questions remain about its biomedical applications, says biomedical engineer Amir Jafari of the University of North Texas in Denton, who was not involved in the work. One big challenge, he says, is precisely controlling magnetic forces inside the human body that are generated from an external device.

    “It’s a compelling tool,” says robotics engineer Nicholas Bira of Harvard University, who was also not involved in the study. But, he adds, scientists who study soft robotics are constantly creating new materials.

    “The true innovation to come lies in combining these different innovative materials.” More

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    Want a ‘Shrinky Dinks’ approach to nano-sized devices? Try hydrogels

    High-tech shrink art may be the key to making tiny electronics, 3-D nanostructures or even holograms for hiding secret messages.

    A new approach to making tiny structures relies on shrinking them down after building them, rather than making them small to begin with, researchers report in the Dec. 23 Science.

    The key is spongelike hydrogel materials that expand or contract in response to surrounding chemicals (SN: 1/20/10). By inscribing patterns in hydrogels with a laser and then shrinking the gels down to about one-thirteenth their original size, the researchers created patterns with details as small as 25 billionths of a meter across.

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    At that level of precision, the researchers could create letters small enough to easily write this entire article along the circumference of a typical human hair.

    Biological scientist Yongxin Zhao and colleagues deposited a variety of materials in the patterns to create nanoscopic images of Chinese zodiac animals. By shrinking the hydrogels after laser etching, several of the images ended up roughly the size of a red blood cell. They included a monkey made of silver, a gold-silver alloy pig, a titanium dioxide snake, an iron oxide dog and a rabbit made of luminescent nanoparticles.

    These two dragons, each roughly 40 micrometers long, were made by depositing cadmium selenide quantum dots onto a laser-etched hydrogel. The red stripes on the left dragon are each just 200 nanometers thick.The Chinese University of Hong Kong, Carnegie Mellon University

    Because the hydrogels can be repeatedly shrunk and expanded with chemical baths, the researchers were also able to create holograms in layers inside a chunk of hydrogel to encode secret information. Shrinking a hydrogel hologram makes it unreadable. “If you want to read it, you have to expand the sample,” says Zhao, of Carnegie Mellon University in Pittsburgh. “But you need to expand it to exactly the same extent” as the original. In effect, knowing how much to expand the hydrogel serves as a key to unlock the information hidden inside.  

    But the most exciting aspect of the research, Zhao says, is the wide range of materials that researchers can use on such minute scales. “We will be able to combine different types of materials together and make truly functional nanodevices.” More

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    This fabric can hear your heartbeat

    Someday our clothing may eavesdrop on the soundtrack of our lives, capturing the noises around and inside us.

    A new fiber acts as a microphone — picking up speech, rustling leaves and chirping birds — and turns those acoustic signals into electrical ones. Woven into a fabric, the material can even hear handclaps and faint sounds, such as its wearer’s heartbeat, researchers report March 16 in Nature. Such fabrics could provide a comfortable, nonintrusive — even fashionable — way to monitor body functions or aid with hearing.

    Acoustic fabrics have existed for perhaps hundreds of years, but they’re used to dampen sound, says Wei Yan, a materials scientist at Nanyang Technological University in Singapore. Fabric as a microphone is “totally a different concept,” says Yan, who worked on the fabric while at MIT.

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    Yan and his colleagues were inspired by the human eardrum. Sound waves cause vibrations in the eardrum, which are converted to electrical signals by the cochlea. “It turns out that this eardrum is made of fibers,” says Yoel Fink, a materials scientist at MIT. In the eardrum’s inner layers, collagen fibers radiate from the center, while others form concentric rings. The crisscrossing fibers play a role in hearing and look similar to the fabrics people weave, Fink says.

    Analogous to what’s happening in an eardrum, sound vibrates fabric at the nanoscale. In the new fabric, cotton fibers and others of a somewhat stiff material called Twaron efficiently convert incoming sound to vibrations. Woven together with these threads is a single fiber that contains a blend of piezoelectric materials, which produce a voltage when pressed or bent (SN: 8/22/17). The buckling and bending of the piezoelectric-containing fiber create electrical signals that can be sent through a tiny circuit board to a device that reads and records the voltage.

    The fabric microphone is sensitive to a range of noise levels, from a quiet library to heavy traffic, the team reports, although it is continuing to investigate what signal processing is needed to detangle target sounds from ambient noise. Integrated into clothing, this sound-sensing fabric feels like regular fabric, Yan says. And it continued to work as a microphone after washing it 10 times.

    Woven into fabric, a specialized fiber (pictured, center) creates electrical signals when bent or buckled, turning the entire material into a microphone.Fink Lab/MIT, Elizabeth Meiklejohn/RISD, Greg Hren

    Piezoelectric materials have “huge potential” for applications from observing the function of bodies to monitoring the integrity of aircraft materials, says Vijay Thakur, a materials scientist at Scotland’s Rural College in Edinburgh who was not part of this work. They’ve even been proposed for energy generation, but, he says, many uses have been limited by the tiny voltages they produce (SN: 10/1/15). The way the fibers are made in this fabric — sandwiching a blend of piezoelectric materials between other components, including a flexible, stretchy outer material — concentrates the energy from the vibrations into the piezoelectric layer, enhancing the signal it produces.

    As a proof of concept, the team incorporated the fabric into a shirt, which could hear its wearer’s heart like a stethoscope does. Used this way, the fabric microphone could listen for murmurs and may someday be able to provide information similar to an echocardiogram, an ultrasound of the heart, Thakur says. If it proves effective as a monitoring and diagnostic tool, placing such microphones into clothing may someday make it easier for doctors to track heart conditions in young children, who have trouble keeping still, he says.

    The team also anticipates that fabric microphones could aid hearing and communication. Another shirt the team created had two piezoelectric fibers spaced apart on the shirt’s back. Based on when each fiber picked up the sound, this shirt can be used to detect the direction a clap came from. And when hooked up to a power source, the fabric microphones can project sound as a speaker.

    “For the past 20 years, we’ve been trying to introduce a new way of thinking about fabrics,” Fink says. Beyond providing beauty and warmth, fabrics may help solve technological problems. And perhaps, Fink says, they can beautify technology too.  More